Ïîñëå ïåðåêðèñòàëëèçàöèè â ïðîöåññå ãàçîñòàòèðîâàíèÿ (ðèñ. 5.4.7, êðèâàÿ 2) ñåëåêòèâíàÿ ïîëîñà ïîãëîùåíèÿ èñ÷åçàåò.  ðàáîòàõ [103,115,149] ïîêàçàíî, ÷òî ãàçîñòàòèðîâàíèå ïðè âûñîêîé òåìïåðàòóðå >10000Ñ ñîïðîâîæäàåòñÿ ïåðåêðèñòàëëèçàöèåé, êîàëåñöåíöèåé ñ îáðàçîâàíèåì ó÷àñòêîâ êðèñòàëëîâ ñ ðàçëè÷íûìè êîíöåíòðàöèÿìè êèñëîðîäà. Ýòî ïðèâîäèò ê íåîäíîðîäíîìó ðàçìûòèþ ïîëîñû.

Äëÿ êðèñòàëëîâ ZnSe â ðàáîòàõ [103,114] ðàñòâîðåííîìó êèñëîðîäó ñîïîñòàâëåíà ïîëîñà ïîãëîùåíèÿ ~ 10 ìêì. Äëÿ ïåðåõîäîâ Å– ® Å+ â ZnSe ýòî ñîîòâåòñòâóåò ðàñùåïëåíèþ 130 ìýÂ, áîëüøåìó, ÷åì çàçîð (ÅÑ – ÅÎ), ðàâíûé 114 ìýÂ. Ñîãëàñíî ñïåêòðàëüíîìó ñìåùåíèþ ýêñèòîííûõ ïîëîñ (~ 10 ìýÂ) êîíöåíòðàöèÿ ðàñòâîðåííîãî êèñëîðîäà â èññëåäîâàííûõ îáðàçöàõ ~ 0,03 ìîë% (1019cì-3), ÷òî ñîãëàñóåòñÿ ñ âåëè÷èíîé ðàñùåïëåíèÿ è ïîäòâåðæäàåòñÿ ðåçóëüòàòàìè àíàëèçîâ íà êèñëîðîä.

 çàâèñèìîñòè îò êîíöåíòðàöèè ðàñòâîðåííîãî êèñëîðîäà ñïåêòðàëüíîå ïîëîæåíèå ïîëîñ ïîãëîùåíèÿ, ñâÿçàííûõ ñ ïåðåõîäàìè Å– ® Å+, ìîæåò áûòü ðàññ÷èòàíî ïî âåëè÷èíå ðàñùåïëåíèÿ çîíû ïðîâîäèìîñòè èç ñîîòíîøåíèÿ (5.4.3), ïðèâåäåííîãî âûøå èëè èç ðèñ. 5.4.8. Ãðàôèê ðèñ. 5.4.8 ïîçâîëÿåò îïðåäåëèòü äèàïàçîí, â êîòîðîì ìîãóò ïðîÿâèòüñÿ ýòè ïîëîñû êàê â îñíîâíîì îáúåìå êðèñòàëëà, òàê è â âûäåëåíèÿõ.

Ðèñ. 5.4.8. Èçìåíåíèå ñïåêòðàëüíîãî ïîëîæåíèÿ ïîëîñ ïîãëîùåíèÿ ZnSe è ZnS, ñâÿçàííûõ ñ ïåðåõîäàìè Å– ® Å+ â çàâèñèìîñòè îò êîíöåíòðàöèè ðàñòâîðåííîãî êèñëîðîäà è âåëè÷èíû ðàñùåïëåíèÿ çîíû ïðîâîäèìîñòè.

 ñâÿçè ñ ýòèì îòìåòèì, ÷òî ñïåêòðû ÈÊ ïðîïóñêàíèÿ ìîãóò äàâàòü èíôîðìàöèþ î ðàñïðåäåëåíèè è ôîðìàõ ïðèñóòñòâèÿ êèñëîðîäà â êðèñòàëëàõ. Òàê, â îáðàçöàõ CVD ZnS, ðàññìîòðåííûõ âûøå, SÀ ñâå÷åíèå âûÿâëÿåò ñêîïëåíèÿ ñî çíà÷èòåëüíî áîëüøåé [OS], ÷åì â îñíîâíîì îáúåìå (ñì. ðàçä. 4.1).  ïðîïóñêàíèè òàêèõ îáðàçöîâ ïðè áîëüøîì êîëè÷åñòâå ñêîïëåíèé ìîãóò ïîÿâëÿòüñÿ äîïîëíèòåëüíûå ïîëîñû ïîãëîùåíèÿ, îáÿçàííûå ñêîïëåíèÿì.

ÍÅ íàøëè? Íå òî? ×òî âû èùåòå?

Ðèñ. 5.4.9. Ñïåêòðû ïðîïóñêàíèÿ ïðè 300Ê CVD ZnSe, ëåãèðîâàííîãî ïðè ðîñòå êèñëîðîäîì, ââåäåííûì â ãàçîâóþ ôàçó â êîëè÷åñòâå 0,9 %. Êðèâàÿ 1 –ýòàëîííûé îáðàçåö, 2 – êîíåö ñì), 3 – ñðåäíÿÿ ÷àñòü êîíäåíñàòà (7 – 9 ñì).

Ñîïîñòàâëåíèå ñïåêòðîâ ñ ñåëåêòèâíûìè ïîëîñàìè (ðèñ. 5.4.9) ïîçâîëÿåò ïî ñìåùåíèþ îäíîòèïíûõ ïîëîñ ïîãëîùåíèÿ ñóäèòü îá èçìåíåíèè â íèõ êîíöåíòðàöèè ðàñòâîðåííîãî êèñëîðîäà. Íàïðèìåð, íà ðèñ. 5.4.9 ïðèâåäåíû òðè ñïåêòðà ïðîïóñêàíèÿ: ýòàëîííîãî îáðàçöà ZnSe (êðèâàÿ 1) è 2-õ ðàçíûõ ó÷àñòêîâ ïðîòÿæåííîãî êîíäåíñàòà (êðèâûå 2 è 3).  öåëîì ñïåêòðû 2-3 ñâèäåòåëüñòâóþò î íåîäíîðîäíîñòè èññëåäóåìîãî êîíäåíñàòà, ïîëó÷åííîãî ïðè ñèëüíîì ëåãèðîâàíèè êèñëîðîäîì ïðè ðîñòå [103]. Äëÿ ZnSe âåñüìà õàðàêòåðíà ïîëîñà ïîãëîùåíèÿ â îáëàñòè ~ 8 ìêì, êîòîðàÿ, ïîâèäèìîìó, ñâÿçàíà ñ ïåðåõîäàìè Å– ® Å+. Îíà íàáëþäàåòñÿ è â ñïåêòðå ýòàëîííîãî îáðàçöà êàê 8,9 ìêì è ñìåùàåòñÿ äëÿ èññëåäóåìûõ îáðàçöîâ äî 8,7 è 8,4 ìêì. Ñìåùåíèå ïîëîñû ñâèäåòåëüñòâóåò îá óâåëè÷åíèè êîíöåíòðàöèè ðàñòâîðåííîãî êèñëîðîäà îò 0,1 ìîë% äî ~ 0,2 ìîë%. Ðàíåå ïðåäïîëàãàëîñü, ÷òî ïîãëîùåíèå, îáÿçàííîå êèñëîðîäó â ÈÊ îáëàñòè, ìîæíî ñîïîñòàâèòü îäíîé, íå ñìåùàþùåéñÿ ñïåêòðàëüíî, ïîëîñå.

Âûâîäû

Ðåçóëüòàòû ðàáîòû ìîãóò áûòü ïðåäñòàâëåíû â âèäå ñëåäóþùèõ îñíîâíûõ âûâîäîâ:

1. Âïåðâûå ïðîâåäåíû èññëåäîâàíèÿ è àíàëèç îñíîâíûõ îïòè÷åñêèõ ñâîéñòâ ñîåäèíåíèé À2Â6 – ZnS è ZnSe – ñ ïðèâëå÷åíèåì òåîðèè àíòèïåðåñåêàþùèõñÿ çîí. Ýòî ïîçâîëèëî ó÷åñòü ïðèñóòñòâèå ôîíîâîé ïðèìåñè êèñëîðîäà, êîòîðàÿ âëèÿåò, äàæå â êîíöåíòðàöèÿõ äî 1 ìîë%, íà çîííóþ ñòðóêòóðó êðèñòàëëà. Ðàññìîòðåíû îñîáåííîñòè ñàìîàêòèâèðîâàííîãî ñâå÷åíèÿ è õàðàêòåðíîå èçìåíåíèå øèðèíû çàïðåùåííîé çîíû â ïðèñóòñòâèè êèñëîðîäà. Àíàëèç ýêñïåðèìåíòàëüíûõ äàííûõ ïîêàçàë, ÷òî ìíîãèå, ðàíåå íå èìåâøèå èíòåðïðåòàöèè îñîáåííîñòè ñïåêòðîâ ëþìèíåñöåíöèè, ïîãëîùåíèÿ, îòðàæåíèÿ è ïðîïóñêàíèÿ, ïîëó÷àþò îáúÿñíåíèå ñ ïîçèöèé òåîðèè àíòèïåðåñåêàþùèõñÿ çîí.

2. Ïðåäëîæåíà çîííàÿ ìîäåëü äëÿ êðèñòàëëîâ ZnS×O, ZnS×Cu(O), ZnSå×O, ZnSå×Cu(O). Ïîäòâåðæäåíî èëè îïðåäåëåíî ïîëîæåíèå óðîâíÿ êèñëîðîäà ÅÎ êàê 0,11 è 0,16 ý ïî îòíîøåíèþ êî äíó çîíû ïðîâîäèìîñòè ÅÑ ÷èñòûõ ñîåäèíåíèé ZnSe è ZnS.  çàâèñèìîñòè îò êîíöåíòðàöèè ðàñòâîðåííîãî êèñëîðîäà ýòà ìîäåëü â ñîãëàñèè ñ ýêñïåðèìåíòàëüíûìè äàííûìè ïîçâîëÿåò îöåíèòü âåëè÷èíû ðàñùåïëåíèÿ çîíû ïðîâîäèìîñòè (D = Å+ – Å–), ñïåêòðàëüíîå ïîëîæåíèå êðàÿ ôóíäàìåíòàëüíîãî ïîãëîùåíèÿ Å–, à òàêæå ïîëîñ SA èëè SAL ñàìîàêòèâèðîâàííîé ëþìèíåñöåíöèè, êàê è ñâÿçàííîãî ýêñèòîíà íà êèñëîðîäíûõ êîìïëåêñàõ.

3. Ïðåäñòàâëåíà íîâàÿ èíòåðïðåòàöèÿ ïîëîñ ëþìèíåñöåíöèè Cu â ñîåäèíåíèÿõ ZnS×O è ZnSe×O, êàê è äóáëåòíîé ñòðóêòóðû ïîëîñ SA è SAL ñàìîàêòèâèðîâàííîãî ñâå÷åíèÿ.

 ÷àñòíîñòè, äâå õîðîøî èçâåñòíûå äëÿ ZnSe ïîëîñû èçëó÷åíèÿ Cu-R è Cu-G îïðåäåëÿþòñÿ îäíèì è òåì æå öåíòðîì, íî îáÿçàíû ïåðåõîäàì èç äâóõ ïîäçîí Å+ è Å– ðàñùåïëåííîé áëàãîäàðÿ ïðèñóòñòâèþ êèñëîðîäà çîíû ïðîâîäèìîñòè.

4. Ïîëó÷åíû ðåçóëüòàòû, õàðàêòåðèçóþùèå ðàñïðåäåëåíèå êèñëîðîäà â êðèñòàëëàõ, êîòîðîå â áîëüøèíñòâå ñëó÷àåâ íåîäíîðîäíîå, ÷òî ñóùåñòâåííî óñëîæíÿåò ñóììàðíûå ñïåêòðû ëþìèíåñöåíöèè è ïîãëîùåíèÿ. Ïðè ýòîì ïîëîñû ñâîáîäíîãî è ñâÿçàííîãî ýêñèòîíà èç ñêîïëåíèé ñ ïîâûøåííûì ñîäåðæàíèåì ðàñòâîðåííîãî êèñëîðîäà îïðåäåëÿþò óçêîëèíåé÷àòûé ñëîæíûé ñïåêòð â êðàåâîé îáëàñòè.

5. Ïîñòðîåíèå ìîäåëè èçëó÷àòåëüíûõ ïåðåõîäîâ, ïîçâîëèëî ïî-íîâîìó ïðåäñòàâèòü ïðèðîäó çåëåíîãî ñâå÷åíèÿ ZnS×Cu. Ïîäòâåðäèëîñü âûñêàçàííîå ðàíåå ïðåäïîëîæåíèå, ÷òî çåëåíîå è ñèíåå ñâå÷åíèå Cu â ZnS îïðåäåëÿþòñÿ ïåðåõîäàìè íà îäèí è òîò æå àêöåïòîðíûé óðîâåíü. Ïðè ýòîì ñïåêòðàëüíîå ïîëîæåíèå çåëåíîé ïîëîñû îïðåäåëÿåòñÿ óìåíüøåíèåì øèðèíû çàïðåùåííîé çîíû Å– â îáëàñòè ñêîïëåíèé êèñëîðîäà. Ýòè âûâîäû ïîäòâåðæäåíû èññëåäîâàíèÿìè ñïåêòðîâ âîçáóæäåíèÿ çåëåíîãî ñâå÷åíèÿ.  ñëó÷àå ZnSå×Cu àíàëîãè÷íûå ïî ïðèðîäå ïîëîñû äîëæíû ñîîòâåòñòâîâàòü ñïåêòðàëüíîìó äèàïàçîíó ~ 700 – 800 íì.

6. Äàíà èäåíòèôèêàöèÿ ïîëîñ ñâÿçàííûõ ýêñèòîíîâ BE íà àêöåïòîðíûõ óðîâíÿõ êèñëîðîäíûõ öåíòðîâ ñàìîàêòèâèðîâàííîãî SA ñâå÷åíèÿ ZnS×O è ZnSe×O. Îáíàðóæåíî, ÷òî ïîëîñû ñâÿçàííûõ íà SA öåíòðàõ ýêñèòîíîâ BESA íàáëþäàþòñÿ â ñïåêòðàõ, ïîëó÷åííûõ èç îáúåìà êðèñòàëëîâ. Ïðè ïîâûøåííîé ïëîòíîñòè âîçáóæäåíèÿ ñîâåðøåííûõ îáðàçöîâ ïîëîñà BESA, ðåçêî óñèëèâàåòñÿ, ñóæàåòñÿ è ïðåâàëèðóåò âî âñåé âèäèìîé îáëàñòè ñïåêòðà. Âûñêàçàíî ïðåäïîëîæåíèå, ÷òî ñâÿçàííûé ýêñèòîí íà êèñëîðîäíûõ öåíòðàõ áóäåò îïðåäåëÿòü ñâå÷åíèå ïðè ëàçåðíîì ýôôåêòå.

7. Èçìåíåíèå çîííîé ñòðóêòóðû, èíèöèèðîâàííîå êèñëîðîäîì, ïðèâîäèò ê óñëîæíåííîé ñèñòåìå óðîâíåé, îïðåäåëÿþùåé ïåðåõîäû ñ ïîãëîùåíèåì. Ïðåäñòàâëåíà ìîäåëü, ñîîòâåòñòâóþùàÿ îñíîâíûì êîìïîíåíòàì ñïåêòðà ïîãëîùåíèÿ (îòðàæåíèÿ, ïðîïóñêàíèÿ), âîçáóæäåíèÿ ëþìèíåñöåíöèè â ñèñòåìå òâåðäûõ ðàñòâîðîâ ZnS×O - ZnSe×O.

Ïîêàçàíî, ÷òî ïðè ââåäåíèè êèñëîðîäà óñèëèâàåòñÿ àáñîðáöèÿ, êîòîðàÿ îáÿçàíà ïåðåõîäàì ÅV ® Å–(+) è õàðàêòåðèçóåòñÿ âåëè÷èíîé êîýôôèöèåíòà ïîãëîùåíèÿ íà óðîâíå ôóíäàìåíòàëüíîãî 5×104-105 ñì-1. Óòî÷íåíû âîçìîæíûå òèïû ïåðåõîäîâ.

Âûäåëåíû ñåëåêòèâíûå ïîëîñû ïîãëîùåíèÿ â áëèæíåì ÈÊ äèàïàçîíå ñïåêòðà, êîòîðûå îïðåäåëÿþòñÿ ïåðåõîäàìè ìåæäó ïîäçîíàìè Å– ® Å+. Ïîêàçàíî, ÷òî ñïåêòðàëüíîå ïîëîæåíèå ýòèõ ïîëîñ çàâèñèò îò êîíöåíòðàöèè êèñëîðîäà. Ïðè íåîäíîðîäíîì ðàñïðåäåëåíèè êèñëîðîäà èìååò ìåñòî èõ ðàçìûòèå.

8. Ïðåäñòàâëåííûå çàâèñèìîñòè ñìåùåíèÿ ýêñèòîííûõ ïîëîñ, êàê è ñàìîàêòèâèðîâàííîé ëþìèíåñöåíöèè, ñ óâåëè÷åíèåì [OS] ìîãóò áûòü èñïîëüçîâàíû äëÿ ïðÿìîãî îïðåäåëåíèÿ êîíöåíòðàöèè ðàñòâîðåííîãî êèñëîðîäà â ZnS èëè â ZnSe â îñíîâíîì îáúåìå êðèñòàëëà (ìàòðèöå) è â ñêîïëåíèÿõ. Ñïåêòðàëüíîå ïîëîæåíèå ýòèõ ïîëîñ ìîæåò áûòü èñïîëüçîâàíî äëÿ êîíòðîëÿ [OS], à òèï ñâå÷åíèÿ – äëÿ îöåíêè îòêëîíåíèÿ ñîñòàâà êðèñòàëëîâ îò ñòåõèîìåòðèè.

Îòìå÷àåòñÿ, ÷òî ïðè áîëüøîì êîýôôèöèåíòå ïîãëîùåíèÿ ñëîæíàÿ ñèñòåìà óðîâíåé ïîâûøàåò ýôôåêòèâíîñòü àáñîðáöèè ñâåòà òâåðäûìè ðàñòâîðàìè ZnS×O è ZnSe×O, ÷òî áëàãîïðèÿòíî äëÿ ñîçäàíèÿ ðÿäà íîâûõ ïðèáîðîâ îïòîýëåêòðîíèêè.

Ïðèíÿòûå îáîçíà÷åíèÿ

(E+ - E–)

Âåëè÷èíà ðàñùåïëåíèÿ çîíû ïðîâîäèìîñòè, èíèöèèðîâàí­íàÿ èçîýëåêòðîííîé ïðèìåñüþ Δ = (E+ - E-), ìýÂ

ΔÅ

Ïîëóøèðèíà ïîëîñ ëþìèíåñöåíöèÿ, ìýÂ

BAC

Àíòèïåðåñåêàþùèåñÿ çîíû (bands anticrossing)

ÂÅ

Ñâÿçàííûé ýêñèòîí

BGB

Ðåçêîå íèñïàäàþùåå èçìåíåíèå çàïðå­ùåííîé çîíû, èíèöèè­ðîâàííûé èçîýëåêòðîííîé ïðèìåñüþ (band gap bowing)

SA(I)

Ñàìîàêòèâèðîâàííàÿ ëþìèíåñöåíöèÿ, îáÿçàííàÿ SA êîìïëåê­ñàì {Zni·×VZn/ /}/× O*S(Se)

Cu(I)

Ñàìîàêòèâèðîâàííàÿ ëþìèíåñöåíöèÿ, îáÿçàííàÿ Cu(I) êîìïëåê­ñàì {Ñui·×VZn/ /}/× O*S(Se)

SAL(II)

Ñàìîàêòèâèðîâàííàÿ ëþìèíåñöåíöèÿ, îáÿçàííàÿ SAL(II) êîìïëåê­ñàì {Zni··×VZn/ /}´× O*S(Se)

Cu(II)

Ñàìîàêòèâèðîâàííàÿ ëþìèíåñöåíöèÿ, îáÿçàííàÿ Cu(II) êîìïëåê­ñàì {Cui··×VZn/ /}´× O*S(Se)

e

Ýíåðãèÿ ñâÿçè ýêñèòîíà

EA

Ïîëîæåíèÿ àêöåïòîðíîãî óðîâíÿ

EO, EN

Óðîâíè èçîýëåêòðîííûõ ïðèìåñåé: êèñëîðîäà, àçîòà â çîííîé ìîäåëè

EC

Çîíà ïðîâîäèìîñòè

Å–

Ìèíèìóì íèæíåé ïîäçîíû (ïðîòÿæåííûõ ñîñòîÿíèé) ðàñ­ùåïëåííîé çîíû ïðîâîäèìîñòè

E+

Ìèíèìóì âåðõíåé ïîäçîíû (ëîêàëèçîâàííûõ ñîñòîÿíèé) ðàñùåïëåííîé çîíû ïðîâîäèìîñòè

FE

Ñâîáîäíûé ýêñèòîí

Í, L

Âûñîêîýíåðãåòè÷åñêàÿ è íèçêîýíåðãåòè÷åñêàÿ ñîñòàâëÿþ­ùèå èçëó÷àòåëüíûõ ïåðåõîäîâ èç ïîäçîí Å+ è Å­– ñîîòâåòñòâåííî

HMAs

òâåðäûå ðàñòâîðû ñ ðåçêèì íåñîîòâåòñòâèåì ñâîéñòâ êîìïî­íåíòîâ (highly mismatched alloys – HMAs), êîãäà èìååò ìå­ñòî èçìåíåíèå çîííîé ñòðóêòóðû

SO

ñïèí-îðáèòàëüíîå ðàñùåïëåíèå

Z

Àòîìíûé (ïîðÿäêîâûé) íîìåð ýëåìåíòà

ÄÂ, ÊÂ

Äëèííîâîëíîâîå, êîðîòêîâîëíîâîå

ÃÑ

Ãàçîñòàòèðîâàíèå – îáðàáîòêà ïðè âûñîêîì äàâëåíèè ãàçà è âûñîêîé òåìïåðàòóðå

ÈÊË

Èìïóëüñíàÿ êàòîäîëþìèíåñöåíöèÿ (ñì. ãë. 2)

ÈÐË

Èìïóëüñíàÿ ðåíòãåíîëþìèíåñöåíöèÿ

ÈÝÏHMAs

Èçîýëåêòðîííàÿ ïðèìåñü çàìåùåíèÿ ñ ðåçêèì íåñîîòâåòñò­âèåì ñâîéñòâ ïî ñðàâíåíèþ ñ àòîìîì ìàòðèöû

ÈÝÀHMAs

Èçîýëåêòðîííûé àêöåïòîð òèïà HMAs

ÈÝÄHMAs

Èçîýëåêòðîííûé äîíîð òèïà HMAs

ÊÄÏ

êðàé “äîïîëíèòåëüíîãî ïîãëîùåíèÿ”, âîçíèêàþùèé íà ñïåê­òðîãðàììàõ ZnS×O, ZnSå×O

ÊË

Êàòîäîëþìèíåñöåíöèÿ

ÌÊË

Ìèêðîêàòîäîëþìèíåñöåíöèÿ (ñúåìêà â ðàñòðîâîì ýëåê­òðîííîì ìèêðîñêîïå)

ÐÝÌ

Ðàñòðîâûé ýëåêòðîííûé ìèêðîñêîï

ÑÒÄ

Ñîáñòâåííûå òî÷å÷íûå äåôåêòû

ÔË

Ôîòîëþìèíåñöåíöèÿ

ÕÃÕ

Õèìè÷åñêèé ãàçîõðîìàòîãðàôè÷åñêèé àíàëèç (ñì. ãë. 2)

ÑÏÈÑÎÊ ÈÑÏÎËÜÇÎÂÀÍÍÛÕ ÈÑÒÎ×ÍÈÊÎÂ

7 , / Êîìïëåêñíîå èññëåäîâàíèå â ÐÝÌ îñîáåííîñòåé èîííîé èìïëàíòàöèè ñóëüôèäà öèíêà // Òåçèñû äîêë. III Ðåñïóáë. êîíô. Ýëåêòðîííàÿ ìèêðîñêîïèÿ è âîïðîñû äèàãíîñòèêè. Êèøèíåâ. Ñ. 152-

8 H. P. Hjalmarson, P. Vogl, D. J. Wolford, J. D. and Dow / Theory of substitutional deep traps in covalent semiconductors // Phys. Rev. Lett. Vol. 44, ¹ 12. P. 810-

9 M. Weyers, M. Sato, H. Ando / Red Shift of Photoluminescence and Absorption in Dilute GaAsN Alloy Layers // Jpn. J. Appl. Phys. Vol. 31. P. L853-L

10 M. Kondow, K. Uomi, A. Niwa, T. Kitatani, et al. / GaInNAs: A Novel Material for Long-Wavelength-Range Laser Diodes with Excellent High-Temperature Performance // Jpn. J. Appl. Phys. Vol. 35. P. 1273-1

11 B. N. Murdin, M. Karmal-Saadi, A. Lindsay, E. P. O`Reilly, et al. / Auger recombination in long-wavelength infrared InNxSb1–x alloys // Appl. Phys. Lett. Vol. 78, ¹ 11. P. 1568-1

12 J. Wu, W. Shan, and W. Walukiewicz / Band anticrossing in highly mismatched III–V semiconductor alloys // Semicond. Sci. Technol. Vol. 17. P. 860-

13 W. Shan, W. Walukiewicz, J. W. Ager III, E. E. Haller, J. F. Geisz, et al. / Band Anticrossing in GaInNAs Alloys // Phys. Rev. Lett. Vol. 82, ¹ 6. P. 1221-1

14 J. W. Ager III and W. Walukiewicz / Current status of research and development of III–N–V semiconductor alloys // Semicond. Sci. Technol. Vol. 17. P. 741-

15 W. Walukiewicz / Narrow band gap group III-nitride alloys // Physica E. Vol. 20. P. 300-

16 J. Wu, W. Walukiewicz and E. E. Haller / Band structure of highly mismatched semiconductor alloys: Coherent potential approximation // Phys. Rev. B. Vol. ).

17 W. Shan, K. M. Yu, W. Walukiewicz, E. E. Haller, M. C. Ridgway, et al. / Reduction of the band-gap energy in GaNAs and AlGaNAs synthesized by N+ implantation // Appl. Phys. Lett. Vol. 75, ¹ 10. P. 1410-1

18 C. Skierbiszewski, P. Perlin, P. Wisniewski, W. Walukiewicz, W. Shan, and J. F. Geisz, et al. / Large, nitrogen-induced increase of the electron effective mass in InyGa1–yNxAs1–x // Appl. Phys. Lett. Vol. 76, ¹ 17. P.  (2000).

19 K. M. Yu, W. Walukiewicz, W. Shan, E. E. Haller, J. F. Geisz, D. J. Friedman, et al. / Nitrogen-induced increase of the maximum electron concentration in group III-N-V alloys // Phys. Rev. B. Vol. 61, ¹ 20, P. R13 337- R13

20 W. Shan, W. Walukiewicz, K. M. Yu, E. E. Haller, H. P. Xin, et al. / Nature of the fundamental band gap in GaNxP1-x alloys // Appl. Phys. Lett. Vol. 76, ¹ 22. P. 3251-3

21 J. D. Perkins, A. Mascarenhas, J. F. Geisz, D. J. Friedman, et al. / Nitrogen- Activated transitions, level repulsion, and band gap reduction in GaAs1-xNx with x < 0,03 // Phys. Rev. Lett. Vol. 82, ¹ 16. P. 3312-3

22 K. M. Yu, W. Walukiewicz, J. Wu, I. Mitkowski, P. Becla, et al. / Band anticrossing in group II-Ox-VI1-x highly mismatched alloys: Cd1-yMnyOxTe1-x quaternaries synthesized by O ion implantation // Appl. Phys. Lett. Vol. 80, ¹ 9. P. 1571-1

23 W. Shan, K. M. Yu, W. Walukiewicz, J. W. Beeman, et al. / Effects of pressure on the band structure of highly mismatched Zn1-yMnyOxTe1-x alloys // Appl. Phys. Lett. Vol. 84, ¹ 6. P. 924-

24 W. Shan, W. Walukiewicz, K. M. Yu, E. E. Haller, Y. Nabetani, et al. / Effect of oxygen on the electronic band structure in ZnOxSe1-x alloys // Appl. Phys. Lett. Vol. 83, ¹ 2. P. 299-

25 Y. Nabetani, T. Mukawa, Y. Ito, T. Kato and T. Matsumoto / Epitaxial growth and large band-gap bowing of ZnSeO alloy // Appl. Phys. Lett. Vol. 83, ¹ 6. P. 1148-1

26 J. Jansinski, K. M. Yu, W. Walukiewicz, J. Washburn, et al. / Influence of microstructure on electrical properties of diluted GaNxAs1-x formed by nitrogen implantation // Appl. Phys. Lett. Vol. 79, ¹ 7. P. 931-

27 K. Uesugi, N. Marooka and I. Suemune / Reexamination of N composition dependence of coherently grown GaNAs band gap energy with high-resolution x-ray diffraction mapping measurements // Appl. Phys. Lett. Vol. 74, ¹ 9. P. 1254-1

28 B. M. Keyes, J. F. Geisz, P. C. Dippo, R. Reedy, C. Kramer, et al. / Optical Investigation of GaNAs // AIP Conference Proceedings 462. Woodbury, NY: American Institute of Physics. P. 511-

29 L. Malikova, F. H. Pollak and R. Bhat / Composition and temperature dependence of the direct band gap of GaAs1-xNx (x ≤ 0,0232) using contactless electroreflectance // J. Electron. Mater. Vol. 27, ¹ 5. P. 484-

30 R. Bhat, C. Caneau, L. Salamanca-Riba, W. Bi, C. Tu / Growth of GaAsN/GaAs, GaInAsN/GaAs and GaInAsN/GaAs quantum wells by low-pressure organometallic chemical vapor deposition // J. Crystal Growth. Vol. 195, ¹ 1-4. P. 427-

31 P. W. Anderson / Localized Magnetic States in Metals // Phys. Rev. Vol. 124. P. 41

32 A. N. Kocharian / Change of valence in rare earth semiconductors in the multiimpurity Anderson model / Sov. Phys. Solid State. Vol. 28. P. 6

33 A. Lindsay, E. P. O`Reilly / Theory of enhanced bandgap non-parabolicity in GaNAs and related alloys // Sol. m. Vol. 112. P. 443-

34 P. Perlin, P. Wisniewski, G. Subramanya, Dan E. Mars, W. Walukiewicz, et al. / Interband optical absorption in free standing layer of Ga0.96In0.04As0.99N0.01 // Appl. Phys. Lett. Vol. 76, ¹ 10. P. 1279-1

35 K. M. Yu, W. Walukiewicz, J. Wu, W. Shan, et al. / Diluted II-VI Oxide Semiconductors with Multiple Band Gaps // Phys. Rev. Lett. Vol. 91, ¹ ).

36 W. Shan, W. Walukiewicz, E. E. Haller, J. F. Geisz, C. Nauka, et al. / Effect of nitrogen on the electronic band structure of group III-N-V alloys // Phys. Rev. B. Vol. 62, ¹ 7. P. 4211-4

37 W. Shan, K. M. Yu, W. Walukiewicz, J. Wu, J. W. Ager III and E. E. Haller / Band anticrossing in dilute nitrides // J. Phys: Condens. Matter. Vol. 16. P. S3355-S3

38 W. Walukiewicz et al., in Proceedings of the 195th meeting of the electrochemical society (The Electrochemical society, Inc., Pennington NJ) Vol. 99-11. P. 190-

39 D. G. Thomas, J. J. Hopfield and C. J. Frosch / Isoelectronic Traps Due to Nitrogen in Gallium Phosphide // Phys. Rev. Lett. Vol. 15. P. 857-

40 D. G. Thomas and J. J. Hopfield / Isoelectronic Traps Due to Nitrogen in Gallium Phosphide // Phys. Rev. Vol. 150. P. 680-

41 J. D. Cuthbert and D. G. Thomas / Fluorescent Decay Times of Excitons Bound to Isoelectronic Traps in GaP and ZnTe // Phys. Rev. Vol. 154. P. 763-

42 J. J. Hopfield, D. G. Thomas and R. T. Lynch / Isoelectronic Donors and Acceptors // Phys. Rev. Lett. Vol. 17. P. 312-

43 J. W. Allen / Isoelectronic impurities in semiconductors: a survey of binding mechanisms // J. Phys. C. Vol. 4. P. 1936-1

44 J. C. Phillips / Cancelation Theorem for Isoelectronic Impurity Binding Energies // Phys. Rev. Lett. Vol. 22. P. 285-

45 J. Wu W. Walukiewicz, K. M. Yu, and J. W. Ager III W. Shan E. E. Haller, et al. / Band anticrossing effects in MgyZn1-yTe1-xSex alloys // Appl. Phys. Lett. Vol. 80, ¹ 1. P. 34

46 K. P. Tchakpele and J. P. Albert / Excitons Bound to Te Impurities in CdS, ZnS, and Their Mixed Compounds with Wurtzite Structure // Phys. Status Solidi B. Vol. 149, ¹ 2. P. 641-

47 W. Walukiewicz, W. Shan, K. M. Yu, M. J. Seong, H. Alawadhi, A. K. Ramdas / Interaction of localized electronic states with the conduction band: band anticrossing in II-VI semiconductor ternaries // Phys. Rev. Lett. Vol. 85, ¹ 7. P. 1552-1

48 M. J. Seong, H. Alawadhi, I. Miotkowski, A. K. Ramdas and S. Miotkowska / The anomalous variation of band gap with alloy composition: cation vs anion substitution in ZnTe // Sol. mun. Vol. 112, ¹ 6. P. 329-

49 M. J. Seong, H. Alawadhi, I. Miotkowski, A. K. Ramdas and S. Miotkowska / Role of electronegativity in semiconductors: Isoelectronic S, Se, and O in ZnTe // Phys. Rev. B. Vol. 62, ¹ 3, P. 1866-1

50 G. W. Iseler and A. J. Strauss / Photoluminescence due to isoelectronic oxygen and tellurium traps in II-IV alloys // J. Lum. Vol. 3. P. 1

51 , / Èçîýëåêòðîííûå ïðèìåñè â ïîëóïðîâîäíèêàõ. Ñîñòîÿíèå ïðîáëåìû. // ÔÒÏ. Ò. 18, â. 8. Ñ. 1345-1

52 M. J. Seong, H. Alawadhi, I. Miotkowski, A. K. Ramdas and S. Miotkowska / Oxygen isoelectronic impurity in ZnSxTe1-x // Phys. Rev. B. Vol. 60, ¹ 24, P. R16 275-R16

53 I. Suemune, K. Uesugi and W. Walukiewicz / Role of nitrogen in the reduced temperature dependence of band-gap energy in GaNAs // Appl. Phys. Lett. Vol. 77, ¹ 19. P. 3021-3

54 K. M. Yu, W. Walukiewicz, W. Shan, J. F.Geisz, M. C. Ridgway, et al. / Nitrogen-induced enhancement of free electron concentration in sulfur implanted GaNxAs1-x // Appl. Phys. Lett. Vol. 77, ¹ 18. P. 2858-2

55 J. Wu, W. Walukiewicz, K. M. Yu, I. Mitkowski, A. K. Ramdas, Ching-Hua Su, et al. / Composition dependence of the hydrostatic pressure coefficients of the bandgap of ZnSe1-xTex allos // Phys. Rev. B. Vol. ).

56 A. Lindsay and E. P. O’Reilly / Influence of nitrogen resonant states on the electronic structure of GaNxAs1-x // Sol. m. Vol. 118. P. 313-

57 J. L. Merz / Isoelectronic Oxygen Trap in ZnTe // Phys. Rev. Vol. 176, ¹ 3. P. 961-

58 R. E. Dietz, D. G. Thomas and J. J. Hopfield / "Mirror" Absorption and Fluorescence in ZnTe // Phys. Rev. Lett. Vol. 8, ¹ 10. P. 391-

59 Jingbo Li and Su-Huai Wei / Alignment of isovalent impurity levels: Oxygen impurity in II-VI semiconductors // Phys. Rev. B. Vol. ).

60 J. Wu, W. Walukiewicz, K. M. Yu, E. E. Haller, et al. / Origin of the band-gap bowing in highly mismatched semiconductor alloys // Phys. Rev. B. Vol. ).

61 J. Wu, W. Walukiewicz, K. M. Yu, J. D. Denlinger, et al. / Valence band hybridization in N-rich GaN1-xAsx alloys // Phys. Rev. B. Vol. ).

62 P. R.C. Kent and A. Zunger / Theory of electronic structure evolution in GaAsN and GaPN alloys // Phys. Rev. B. Vol. ).

63 J. Endicott, A. Patane, M. Hopkinson, R. Airey, et al. / Magnetotunneling spectroscopy of dilute Ga(AsN) quantum wells // Phys. Rev. Lett. Vol. 91, ¹ ).

64 A. Patane, J. Endicott, S. B. Healy, A. Lindsay, M. Hopkinson, et al. / Breakup of the conduction band structure of dilute GaAs1-yNy alloys // Phys. Rev. B. Vol. ).

65 P. J. Klar, H. Gruning, W. Heimbrodt, J. Koch, F. Hohnsdorf, W. Stolz, et al. / From N isoelectronic impurities to N-induced bands in the GaNxAs1-x alloy // Appl. Phys. Lett. Vol. 76. P. 3439-3

66 Klar, P. J., Gruning, H., Heimbrodt, W., Weiser, G., Koch, O’Reilly, E. P., Hofmann, et al. / Interband transitions of quantum wells and device structures containing Ga(N, As) and (Ga, In)(N, As) // Semicond. Sci. Technol. Vol. 17. P. 830-

67 X. Liu, M.-E. Pistol, L. Samuelson, S. Schwetlick, and W. Seifert / Nitrogen pair luminescence in GaAs // Appl. Phys. Lett. Vol. 56. P. 1451-1

68 S. B. Healy, A. Lindsay and E. P. O’Reilly / Influence of cluster states on band dispersion in bulk and quantum well (ultra-)dilute nitride semiconductors // IEE Proc.-Optoelectron. Vol. 151, ¹ 5, P. 397-

69 P. R.C. Kent, L. Bellaiche and A. Zunger / Pseudopotential theory of dilute III-V nitrides // Semicond. Sci. Technol. Vol. 17. P. 851-

70 A. Lindsay and E. P. O’Reilly / A tight-binding based analysis of the band anti-crossing model in GaNxAs1-x // Physica E. Vol. 21. P. 901-

71 , , / Ñïåêòðàëüíîå èññëåäîâàíèå ýíåðãåòè÷åñêîé ñòðóêòóðû ñìåøàííûõ ìîíîêðèñòàëëîâ CdSexTe1-x // ÔÒÏ. Ò. 6, â. 4. Ñ. 698-

72 , , / Èññëåäîâàíèå ýíåðãåòè÷åñêîé ñòðóêòóðû ñìåøàííûõ ìîíîêðèñòàëëîâ CdSxTe1-x // Ôèçèêà ïîëóïðîâîäíèêîâ. Ò. 10, â. 6. Ñ. 1193-1

73 / Òâåðäûå ðàñòâîðû (ZnTe)x(CdSe)1-x Ñïåêòðàëüíîå èññëåäîâàíèå ýíåðãåòè÷åñêîé ñòðóêòóðû ñìåøàííûõ ìîíîêðèñòàëëîâ CdSexTe1-x // ÔÒÏ. Ò. 6, â. 4. Ñ. 698-

74 , / Îáðàáîòêà ïîðîøêîâûõ ðåíòãåíîãðàìì íåñîâåðøåííûõ ìîíîêðèñòàëëîâ ìåòîäîì íàèìåíüøèõ êâàäðàòîâ // Ñá. Òðóäû ÌÈÈÒ. ¹ 000. Ñ. 113-

75 / Èññëåäîâàíèå è ðàçðàáîòêà íåéòðîííî-àêòèâàöèîííûõ ìåòîäîâ îïðåäåëåíèÿ íåêîòîðûõ ëåãêèõ ýëåìåíòîâ // Äèñ. êàíä. òåõí. íàóê. – Ì.: ÖÍÈÈ×åðìåò èì. Áàðäèíà, 1968.

76 / Òåðìîäèíàìèêà ïîâåäåíèÿ êèñëîðîäà â ñîåäèíåíèÿõ A2B6 â ïðîöåññå õèìè÷åñêîãî àíàëèçà ñ èñïîëüçîâàíèåì ãàçîâîé õðîìàòîãðàôèè // Ìàã. Äèñ. – Ì.: ÌÝÈ. 1999.

77 J. Wu, W. Walukiewicz, K. M. Yu, J. W. Ager III, S. X. Li, E. E. Haller, Hai Lu, William J. Schaff. / Universal bandgap bowing in group-III nitride alloys // Sol. m. Vol. 127. P. 411-

78 S. X. Li, E. E. Haller, K. M. Yu, W. Walukiewicz, J. W. Ager III, J. Wu, W. Shan, Hai Lu and William J. Schaff. / Effect of Native Defects on Optical Properties of InxGa1-xN Alloys // Lawrence Berkeley National Laboratory, Paper LBNL-57

79 ,  , è äð. / Îïòè÷åñêàÿ ñïåêòðîñêîïèÿ ãëóáîêèõ ñîñòîÿíèé â ZnTe // ÔÒÒ. Ò. 40, â. 6. Ñ. 1010-1

80 F. A. Kroeger and J. A.M. Dikhoff / The function of oxygen in Zinc Sulfide Phosphors // J. of the Electrochemical Soc. Vol. 99, ¹ 4. P. 144-

81 , , / Î öåíòðàõ ëþìèíåñöåíöèè ñàìîàêòèâèðîâàííîãî ZnS è ZnS–O, Cu // Òð. ÔÈÀÍ. Ò. 138. Ñ. 157-

82 , , / Ýëåêòðîííûå âîçáóæäåíèÿ è ðàäèîëþìèíåñöåíöèÿ ùåëî÷íî-ãàëîèäíûõ êðèñòàëëîâ // Ðèãà: Çèíàòíå, 1979.

83 Ýêñèòîíû / Ïîä. ðåä. , // Ì.: Íàóêà, 1985.

84 M. Hanke, D. Henning, A. Kaschte / A tight-binding description of isovalent impurity clusters // Phys. Stat. Sol. (b). Vol. 143. P. 665-

85 , , / Ñîñóùåñòâîâàíèå ñâÿçàííûõ ñ äåôåêòàìè ýêñèòîíîâ áîëüøîãî è ìàëîãî ðàäèóñà â òâåðäûõ òåëàõ // Ïèñüìà â ÆÝÒÔ. Ò. 39, â. 2. Ñ. 54

86 , , / Ýêñèòîííûå ñïåêòðû òâåðäîãî ðàñòâîðà ZnSe1-xTex // ÔÒÒ. Ò. 29, â. 2. Ñ. 337-

87 U. Flesh, R. A. Hoffman and R. Rass / Exciton luminescence of cubic ZnS crystals // J. Lumines. ¹ 3. P. 137-

88 Ôèçèêà è õèìèÿ ñîåäèíåíèé ÀIIÂVI / Ïîä. ðåä. Ì. Àâåíà // Ì.: Ìèð, 1970.

89 / Õèìèÿ íåñîâåðøåííûõ êðèñòàëëîâ // Ì.: Ìèð, 1969.

90 / Âëèÿíèå ñëîæíîãî ëåãèðîâàíèÿ èçîýëåêòðîííûìè ïðèìåñÿìè êèñëîðîäà è òåëëóðà íà îïòè÷åñêèå ñâîéñòâà ñóëüôèäà êàäìèÿ è ñåëåíèäà öèíêà // Äèñ. êàíä. ôèç.-ìàò. íàóê. – Ì.: ÌÝÈ, 1995.

91 , / Ñóëüôèä öèíêà. Ïîëó÷åíèå è îïòè÷åñêèå ñâîéñòâà // Ïîä. ðåä.  Â. – Ì.: Íàóêà, 1987.

92 W. Van Gool / Fluorescent centers in ZnS // Phys. Res. Reð. Suppl. ¹ 3. P. 1-

93 , , / Î ðàñòâîðèìîñòè êèñëîðîäà â CdS // Íåîðãàí. ìàòåð. Ò. 29, ¹ 7. C. 1014-1

94 , ,  / Ýêñèòîííûé ñïåêòð CdS ñ êîíòðîëèðóåìûì èçìåíåíèåì ñòåõèîìåò­ðèè è êîíöåíòðàöèè êèñëîðîäà // ÆÏÑ. Ò. 60, ¹ 3. C. 341-

95 , , / Îïðåäåëåíèå ñîäåðæàíèÿ êèñëîðîäà â ñîåäèíåíèÿõ À2Â6 êèíåòè÷åñêèì ìåòîäîì ñ èñïîëüçîâàíèåì ãàçîâîé õðîìàòîãðàôèè // Äîêë. ìåæä. íàó÷.-òåõ. 30 ñåìèíàðà "Øóìîâûå è äåãðàäàöèîííûå ïðîöåññû â ïîëóïðîâîäíèêîâûõ ïðèáîðàõ". Ì.: ÌÝÈ. Ñ. 211-

96 , Íàçàðîâà Ê. Í. / Èçìåíåíèå ñîáñòâåííî-äåôåêòíîé ñòðóêòóðû CdS (ZnSe) ïðè ëåãèðîâàíèè èçîýëåêòðîííûìè ïðèìåñÿìè O è Te // Íåîðãàí. ìàòåð. Ò. 32, ¹ 5. Ñ. 542-

97 / Èññëåäîâàíèå öèíêñóëüôèäíûõ ëþìèíîôîðîâ, àêòèâèðîâàííûõ êèñëîðîäîì // Äèñ. êàíä. õèì. íàóê. – Ì.: ÌÕÒÈ, 1974.

98 , ,  è äð. / Ñåëåíèä öèíêà. Ïîëó÷åíèå è îïòè÷åñêèå ñâîéñòâà // Ïîä. ðåä. – Ì.: Íàóêà, 1992.

99 , / Ñâÿçàííàÿ ñ êèñëîðîäîì ëþìèíåñöåíöèÿ "áåñïðèìåñíîãî" ZnS // ÆÏÑ. Ò. 17, ¹ 2. Ñ. 261-

100 / Êèñëîðîä â ñóëüôèäå êàäìèÿ è åãî âëèÿíèå íà îïòè÷åñêèå ñâîéñòâà // Äèñ. êàíä. ôèç.-ìàò. íàóê. – Ì.: ÌÝÈ, 1993.

101 / Îïòè÷åñêèå ñâîéñòâà ñåëåíèäà öèíêà, ñîäåðæàùåãî êèñëîðîä // Äèñ. êàíä. ôèç.-ìàò. íàóê. – Ì.: ÌÝÈ, 1986.

Èç çà áîëüøîãî îáúåìà ýòîò ìàòåðèàë ðàçìåùåí íà íåñêîëüêèõ ñòðàíèöàõ:
1 2 3 4 5 6 7 8 9